Application of Bentonite-Based Sediment Capping for Eutrophication Control: A Case Study of Lake Batur, Bali

Authors

  • Annisa Rehan Fadhila Institut Teknologi Sumatera Author
  • Irhamni Institute Teknologi Sumatera Author
  • Astried Sunaryani Institute Teknologi Sumatera Author

Keywords:

sediment capping, bentonite, phosphate,, nitrogen, lake batur

Abstract

Increasing nutrient inputs, particularly phosphate and nitrogen, have contributed to eutrophication in Lake Batur and increased the risk of water quality degradation. This study evaluated the effectiveness of sediment capping using activated and non-activated bentonite for nutrient removal, including total phosphorus (TP), total nitrogen (TN), nitrate, and ammonia. Characterization using SEM-EDX and FTIR showed that the activation process altered the surface morphology and chemical properties of bentonite, resulting in a more open structure and higher silicon and aluminum contents. Shifts in the absorption bands of –OH, Si–OH, and Si–O–Si groups indicated surface modification without damaging the montmorillonite framework. The results demonstrated that non-activated bentonite achieved the highest removal efficiency for total phosphorus, reaching 87%. Activated bentonite showed better performance in reducing total nitrogen and nitrate, with removal efficiencies of 61% and 79%, respectively. Meanwhile, nitrate removal by non-activated bentonite reached 78%. Ammonia removal remained relatively limited, where activated bentonite reduced ammonia concentration by 30%, while non-activated bentonite showed a slight increase in ammonia concentration of −12%. Overall, both activated and non-activated bentonite exhibited potential as sediment capping materials for controlling nutrient release in aquatic systems.

References

[1] Arik Agustina and N. P. I. Aprinica, “Dampak pariwisata terhadap pencemaran air danau batur kabupaten bangli,” Jurnal Ilmiah Hospitality Management, vol. 12, no. 2, pp. 81–89, 2022, doi: 10.22334/jihm.v12i2.189.

[2] R. I. Dewi, “Persepsi Masyarakat Terhadap Keunikan Alam Danau Batur Bali,” Jurnal Green Growth dan Manajemen Lingkungan, vol. 9, no. 1, pp. 18–25, 2020, doi: 10.21009/jgg.091.03.

[3] A. Lusia, T. Prayogo, S. Zulaikha, L. Widodo, and Y. S. Garno, “Perception of the Farming Community on Benefits and Environmental Conditions of Lake Batur,” Jurnal Teknologi Lingkungan, vol. 24, no. 2, pp. 228–234, 2023.

[4] A. Sunaryani, A. B. Santoso, P. Soewondo, Suharyanto, A. Imananda, and I. F. Sani, “Eutrophication in Lake Batur: current status and management strategies,” E3S Web of Conferences, vol. 485, no. 60, pp. 1–10, 2024, doi: 10.1051/e3sconf/202448503013.

[5] I. Febriana Sani, A. Sunaryani, and R. Utami, “Identifikasi Kualitas Air dan Pencemaran Nutrien di Danau Batur dari Parameter Total Fosfat dan Total Nitrogen,” Jurnal Tekonologi Lingkungan , vol. 25, no. 2, p. 325, 2024.

[6] M. S. Yusal, M. A. Marfai, S. Hadisusanto, and N. Khakhim, “Abundance of Meiofauna and Physical-Chemical Parameters as Water Quality Indicator,” Ilmu Kelautan: Indonesian Journal of Marine Sciences, vol. 24, no. 2, pp. 81–90, 2019, doi: 10.14710/ik.ijms.24.2.81-90.

[7] H. S. Ayele and M. Atlabachew, “Review of characterization, factors, impacts, and solutions of Lake eutrophication: lesson for lake Tana, Ethiopia,” Environmental Science and Pollution Research, vol. 28, no. 12, pp. 14233–14252, 2021, doi: 10.1007/s11356-020-12081-4.

[8] D. Anggraini, P. S.A., and D. A. Wulandari, “Analisis Ekonomi Pengendalian Sedimentasi Waduk Mrica,” Briliant: Jurnal Riset dan Konseptual, vol. 4, no. 4, p. 567, 2019, doi: 10.28926/briliant.v4i4.378.

[9] M. Mulyadi and A. M. S. Yunus, “Pengembangan Desain Aerator Terapung Sistem Panel Surya,” Prosiding Seminar Hasil Penenilitian (SNP2M), vol. 2017, pp. 41–46, 2017.

[10] I. Melati, “Teknik Bioremediasi: Keuntungan, Keterbatasan Dan Prospek Riset,” Prosiding Seminar Biotik, no. Rahayu 2005, pp. 272–286, 2020.

[11] M. K. Aliyu, A. T. B. A. Karim, C. M. Chan, A. Abdulkadir, Z. Bin Daud, and A. A. Oyekanmi, “Active Capping Treatment of Copper and Chromium Contaminated Sediment with Bentonite Kaolin and Sand to Inhibit their Release to the Overlying Water,” Journal of Ecological Engineering, vol. 23, no. 12, pp. 264–272, 2022, doi: 10.12911/22998993/153395.

[12] Z. Liu, Y. Zhang, Q. Zhou, Z. Wu, and Y. Wang, “In-situ Technologies for Controlling Sediment Phosphorus in Eutrophic Shallow Lakes: A Review,” Journal of Earth Science, vol. 36, no. 1, pp. 113–133, 2025, doi: 10.1007/s12583-024-0118-9.

[13] A. Sunaryani, P. Soewondo, and A. B. Santoso, “Sediment capping technology for eutrophication control and its potential for application in Indonesian lakes: a review,” LIMNOTEK Perairan Darat Tropis di Indonesia, vol. 29, no. 1, 2023, doi: 10.55981/limnotek.2023.2366.

[14] D. A. Setyorini, M. Burhannudinnur, M. Ginting, R. Adhitama, and E. S. D. Saribu, “Pelatihan Penjernihan Air Tanah Menggunakan Alat Filtrasi Air di Desa Sungai Dayo, Provinsi Jambi,” Jurnal Abdi Masyarakat Indonesia (JAMIN), vol. 4, no. 2, 2022, doi: 10.25105/jamin.v4i2.14796.

[15] V. V. Krupskaya et al., “Experimental study of montmorillonite structure and transformation of its properties under treatment with inorganic acid solutions,” Minerals, vol. 7, no. 4, pp. 1–15, 2017, doi: 10.3390/min7040049.

[16] N. Hodzic, A. Dozic, I. Sestan, and H. Alihodzic, “Examination of Adsorption Abilities of Natural and Acid Activated Bentonite for Heavy Metals Removal from Aqueous Solutions,” International Journal For Research in Applied Sciences and Biotechnology, vol. 07, no. 01, pp. 1–6, 2020, doi: 10.31033/ijrasb.7.1.1.

[17] D. Andini, Y. Martin, and H. Gusmedi, “Perbaikan Tahanan Pentanahan dengan Menggunakan Bentonit Teraktivasi,” Electrician – Jurnal Rekayasa dan Teknologi Elektro, vol. 10, no. 1, pp. 44–53, 2016.

[18] American Public Health Association (APHA), Standard Methods 4500-P Phosphorus. 2012.

[19] A. Satya, T. Chrismadha, A. D. M. Satya, and I. A. Satya, “Optimizing crude protein production from minute duckweed (Lemna perpusilla Torr) grown in varied NPK based medium,” IOP Conference Series: Earth and Environmental Science, vol. 1062, no. 1, 2022, doi: 10.1088/1755-1315/1062/1/012008.

[20] American Public Health Association (APHA), Standard Methods 4500-NO3. 1992.

[21] SNI. 06-6989.30-2005, Cara Uji Ammonia dengan Spektrofotometer secara Fenat. 2005.

[22] M. Toor and B. Jin, “Adsorption characteristics, isotherm, kinetics, and diffusion of modified natural bentonite for removing diazo dye,” Chemical Engineering Journal, vol. 187, pp. 79–88, 2012, doi: 10.1016/j.cej.2012.01.089.

[23] S. Osmić, A. Odobašić, and S. Begić, “The Influence of Acid Activation on Surface Characteristics of Natural Bentonite,” in International Research Journal of Pure and Applied Chemistry, 2024, pp. 35–42. doi: https://doi.org/10.9734/irjpac/2024/v25i5873.

[24] S. Rades, V. D. Hodoroaba, and T. Salge, “High-resolution imaging with SEM/T-SEM, EDX and SAM as a combined methodical approach for morphological and elemental analyses of single engineered nanoparticles,” RSC Advances, vol. 4, no. 91, pp. 49577–49587, 2014, doi: 10.1039/c4ra05092d.

[25] M. T. Berhe, G. G. Berhe, M. S. Cheru, and M. G. Weldehans, “Characterization of Acid Activation of Bentonite Clay of Hadar, Afar, Ethiopia,” Advances in Materials Science and Engineering, vol. 2024, 2024, doi: 10.1155/2024/6413786.

[26] N. T. Berghuis, M. Mutaqqin, and F. I. Hidayat, “Perbandingan Penggunaan Katalis Alam (Zeolit dan Bentonit) dalam Sintesis Biodiesel dari Minyak Goreng Komersil,” ALCHEMY Jurnal Penelitian Kimia, vol. 18, no. 2, p. 174, 2022, doi: 10.20961/alchemy.18.2.57616.174-182.

[27] M. T. Caccamo, G. Mavilia, L. Mavilia, D. Lombardo, and S. Magazù, “Self-assembly processes in hydrated montmorillonite by FTIR investigations,” Materials, vol. 13, no. 5, 2020, doi: 10.3390/ma13051100.

[28] T. Koestiari, “Perbedaan Karakter Tiga Jenis Bentonit Ditinjau dari Tiga Macam Cara Analisis,” Jurnal Kimia Riset, vol. 1, no. 2, pp. 57–63, 2013.

[29] R. Mohadi, Y. M. Hakim, R. D. Astuti, I. Royani, and M. Mardiyanto, “Pillarization of Sumatera Bentonite by Sodium-assisted as Effective Adsorbent of Anionic Surfactants Sodium Lauryl Sulphate (SLS) Waste,” Bulletin of Chemical Reaction Engineering and Catalysis, vol. 18, no. 1, pp. 48–58, 2023, doi: 10.9767/bcrec.16500.

[30] D. Ghafarunnisa, “Identifikasi Keterdapatan Potensi Bahan Galian Kuarsa di Kelurahan Padang, Kecamatan Sukamara, Kabupaten Sukamara,” Jurnal Simetrik, pp. 120–127, 2025.

[31] M. Hafiduddin and A. Nugrahini, “Analisis Mineral Plagioklas untuk Menentukan Pembekuan Lava Daerah Kenalan, Kecamatan Borobudur, Kabupaten Magelang, Provinsi Jawa Tengah,” Jurnal ReTII, vol. 18, no. 1, pp. 549–555, 2023.

[32] K. Kelts and K. J. Hsü, “Freshwater Carbonate Sedimentation,” Lakes, pp. 295–323, 1978, doi: 10.1007/978-1-4757-1152-3_9.

[33] Z. Cui, H. Fang, L. Huang, K. Ni, and D. Reible, “Effect of surface heterogeneity on phosphorus adsorption onto mineral particles: experiments and modeling,” Journal of Soils and Sediments, vol. 17, no. 12, pp. 2887–2898, 2017, doi: 10.1007/s11368-017-1746-9.

[34] P. Komadel and J. Madejová, Acid activation of clay minerals, 2nd ed., vol. 5. Elsevier Ltd., 2013. doi: 10.1016/B978-0-08-098258-8.00013-4.

[35] Peraturan Pemerintah No. 22 Tahun 2021, “Lampiran VI tentang Baku Mutu Air Nasional - PP Nomor 22 Tahun 2021 Tentang Penyelenggaraan Perlindungan dan Pengelolaan Lingkungan Hidup,” Sekretariat Negara Republik Indonesia, 2021.

[36] P. C. Kavcar and S. J. Wright, “Effects of gas ebullition on cohesive sediment resuspension and cap stability,” Proceedings of World Environmental and Water Resources Congress 2009 - World Environmental and Water Resources Congress 2009: Great Rivers, vol. 342, pp. 3471–3480, 2009, doi: 10.1061/41036(342)351.

[37] S. Sufriadin, P. Purwanto, N. P. Rapele, C. Sastria, and S. S. Fauth, “Analisis Mineralogi dan Kimia Bentonit Daerah Bone Bolango, Provinsi Gorontalo,” Jurnal Geomine, vol. 8, no. 2, pp. 104–113, 2020, doi: 10.33536/jg.v8i2.604.

[38] P. Kumar, R. V. Jasra, and T. S. G. Bhat, “Evolution of Porosity and Surface Acidity in Montmorillonite Clay on Acid Activation,” Industrial and Engineering Chemistry Research, vol. 34, no. 4, pp. 1440–1448, 1995, doi: 10.1021/ie00043a053.

[39] A. Patel, E. D. C. Hingston, and M. Demlie, “Investigation of the suitability of activated and non-activated bentonites from the Imerys Mine (South Africa) for geosynthetic clay liners,” South African Journal of Science, vol. 118, no. 11–12, pp. 1–8, 2022, doi: 10.17159/sajs.2022/12566.

[40] Y. Dong, H. Zhai, Z. Gao, G. Gong, and F. Li, “Study on the preparation of calcium modified coal gangue and its adsorption performance of phosphate,” Scientific Reports, vol. 15, no. 1, pp. 1–13, 2025, doi: 10.1038/s41598-025-86435-8.

[41] M. R. Abukhadra, S. M. Ali, E. A. Nasr, H. A. A. Mahmoud, and E. M. Awwad, “Effective Sequestration of Phosphate and Ammonium Ions by the Bentonite/Zeolite Na-P Composite as a Simple Technique to Control the Eutrophication Phenomenon: Realistic Studies,” ACS Omega, vol. 5, no. 24, pp. 14656–14668, 2020, doi: 10.1021/acsomega.0c01399.

[42] N. Nafsiyah, A. Shofiyani, and I. Syahbanu, “Studi Kinetika dan Isoterm Adsorpsi Fe(III) pada Bentonit Teraktivasi Asam Sulfat,” Jurnal Kimia dan Kemasan, vol. 6, no. 1, pp. 57–63, 2017.

[43] B. J. Allred, J. M. Bigham, and G. O. Brown, “The Impact of Clay Mineralogy on Nitrate Mobility under Unsaturated Flow Conditions,” Vadose Zone Journal, vol. 6, no. 2, pp. 221–232, 2007, doi: 10.2136/vzj2006.0064.

[44] O. Kheliel, L. Youcef, S. Youcef, M. G. Bouaziz, and M. Chebbi, “Efficiency of Nitrate Removal from Groundwater by Adsorption on Raw and Treated Bentonite,” Nitrogen (Switzerland), vol. 6, no. 1, 2025, doi: 10.3390/nitrogen6010006.

[45] S. Ansari, R. Bello-Mendoza, A. O’Sullivan, S. Basharat, and D. Barker, “Nitrate and phosphate removal from water using a novel cellulose-based anion exchange hydrogel,” Environmental Technology and Innovation, vol. 39, no. July, p. 104289, 2025, doi: 10.1016/j.eti.2025.104289.

[46] Y. Angar, N. E. Djelali, and S. Kebbouche-Gana, “Investigation of ammonium adsorption on Algerian natural bentonite,” Environmental Science and Pollution Research, vol. 24, no. 12, pp. 11078–11089, 2017, doi: 10.1007/s11356-016-6500-0.

[47] A. Alshameri, H. He, and Z. Jianxi, “Adsorption of ammonium by different natural clay minerals: Characterization, kinetics and adsorption isotherms,” Applied Clay Science, vol. 159, no. August, pp. 83–93, 2018, doi: 10.1016/j.clay.2017.11.007.

[48] K. Wu, Y. Li, and T. Liu, “Evaluation of the adsorption of ammonium-nitrogen and phosphate on a granular composite adsorbent derived from zeolite,” Environmental Science and Pollution Research, vol. 26, no. 17, pp. 17632–17643, 2019, doi: 10.1007/s11356-019-05069-2.

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29/07/2026

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[1]
“Application of Bentonite-Based Sediment Capping for Eutrophication Control: A Case Study of Lake Batur, Bali”, jse, vol. 11, no. 3, Jul. 2026, Accessed: Jul. 31, 2026. [Online]. Available: http://jse.serambimekkah.id/index.php/jse/article/view/2015

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