Efektivitas Delignifikasi Limbah Mesokarp Kelapa Sawit untuk Meningkatkan Potensi Selulosa

Authors

  • Rizka Ayu Yuniar Institut teknologi Kalimantan Author
  • Esty Purwati Institut Teknologi Kalimantan Author
  • Borneo Bayu Samudera Institut Teknologi Kalimantan Author
  • Jefri Pandu Hidayat Institut Teknologi Kalimantan Author

Keywords:

material, delignification, cellulose, lignin, kappa number

Abstract

Biomass-based products are increasingly being used in industrial applications, but these innovations require efficient pretreatment to standardise the raw materials. In this study, the characteristics of oil palm mesocarp fibres after alkali processing were evaluated. The process consisted of two stages: delignification and bleaching. The organosolv extraction method was used to increase the efficiency of delignification during the bleaching stage. The mesocarp fibres were analysed using the kappa number test, scanning electron microscopy and Fourier transform infrared spectroscopy. A decrease in kappa number was observed, indicating a lower lignin content in the mesocarp samples. The FTIR spectrum showed a decrease in the peak intensity of C=C bonds in lignin at wavelengths of 1400-1500 cm-¹. Structural changes in fibre morphology after delignification and bleaching were observed, indicating that lignin had been successfully extracted from the mesocarp fibres. Optimal conditions for kappa number reduction were obtained at a NaOH concentration of 1 M, a delignification time of 4 h and a NaOCl volume of 280 ml (28 ml/g).

References

[1] E. T. Awoh, J. Kiplagat, S. K. Kimutai, and A. C. Mecha, “Current trends in palm oil waste management: A comparative review of Cameroon and Malaysia,” Nov. 01, 2023, Elsevier Ltd. doi: 10.1016/j.heliyon.2023.e21410.

[2] L. , H. Wicaksono, M. G. Arrahim, and Fadhillah A. R., “Recycling Oil Palm Industry Waste : Sustainable solid Waste Treatment Utilizing Bioconversion Agent,” Journal of Science and Applied Engineering, vol. 4, no. 2, pp. 51–54, 2022, doi: 10.1016/j.egypro.2013.05.005.

[3] Mahidin et al., “Analysis of power from palm oil solid waste for biomass power plants: A case study in Aceh Province,” Chemosphere, vol. 253, p. 126714, 2020, doi: https://doi.org/10.1016/j.chemosphere.2020.126714.

[4] E. Rahmilaila Desfitri, A. Yoga Arifanda, A. Yulianti, and R. Desmiarti, “Studi Efektivitas Pemanfaatan Arang Aktif Cangkang Kelapa Sawit (Elaeis guineensis) Sebagai Adsorben Pengurangan Kadar Amonia Limbah Cair Tahu Effectivity Study of Palm Shell Activated Charcoal Utilization (Elaeis guineensis) as Adsorbent for Reducing Ammonia Concentration in Tofu Liquid Waste,” 2024.

[5] T. Saepoo, S. Sarak, J. Mayakun, T. Eksomtramage, and K. Kaewtatip, “Thermoplastic starch composite with oil palm mesocarp fiber waste and its application as biodegradable seeding pot,” Carbohydr Polym, vol. 299, p. 120221, 2023, doi: https://doi.org/10.1016/j.carbpol.2022.120221.

[6] J. H. Ling, Y. T. Lim, W. K. Leong, and H. T. Sia, “Utilization of Oil Palm Empty Fruit Bunch in Cement Bricks,” Journal of Advanced Civil and Environmental Engineering, vol. 4, no. 1, p. 1, Apr. 2021, doi: 10.30659/jacee.4.1.1-10.

[7] L. Indriati, N. Elyani, and S. F. Dina, “Empty fruit bunches, potential fiber source for Indonesian pulp and paper industry,” in IOP Conference Series: Materials Science and Engineering, IOP Publishing Ltd, Dec. 2020. doi: 10.1088/1757-899X/980/1/012045.

[8] Sumila, Sumila, Asifa Asri, and Dwiria Wahyuni. "Uji Kinerja Karbon Aktif Tandan Kosong Kelapa Sawit (Tkks) Sebagai Reusable Adsorbent Logam Besi Pada Air Gambut." Jurnal Fisika: Fisika Sains dan Aplikasinya 8.2 (2023): 17-22

[9] T. A. T. Yasim-Anuar, H. Ariffin, M. N. F. Norrrahim, and M. A. Hassan, “Factors affecting spinnability of oil palm mesocarp fiber cellulose solution for the production of microfiber,” Bioresources, vol. 12, no. 1, pp. 715–734, 2017, doi: 10.15376/biores.12.1.715-734.

[10] A. D. French, “Glucose, not cellobiose, is the repeating unit of cellulose and why that is important,” Cellulose, vol. 24, no. 11, pp. 4605–4609, 2017, doi: 10.1007/s10570-017-1450-3.

[11] M. Scott, P. J. Deuss, J. G. De Vries, M. H. G. Prechtl, and K. Barta, “New insights into the catalytic cleavage of the lignin β-O-4 linkage in multifunctional ionic liquid media,” Catal Sci Technol, vol. 6, no. 6, pp. 1882–1891, 2016, doi: 10.1039/c5cy01554e.

[12] C. Huang, W. Lin, C. Lai, X. Li, Y. Jin, and Q. Yong, “Coupling the post-extraction process to remove residual lignin and alter the recalcitrant structures for improving the enzymatic digestibility of acid-pretreated bamboo residues,” Bioresour Technol, vol. 285, p. 121355, 2019, doi: https://doi.org/10.1016/j.biortech.2019.121355.

[13] V. R. Seleš, I. Bates, I. Plazonić, and I. Majnarić, “Analysis Of Optical Properties Of Laboratory Papers Made From Straw Pulp And Coated With Titanium Dioxide White Ink,” 2020.

[14] E. Małachowska, M. Dubowik, A. Lipkiewicz, K. Przybysz, and P. Przybysz, “Analysis of cellulose pulp characteristics and processing parameters for efficient paper production,” Sustainability (Switzerland), vol. 12, no. 17, Sep. 2020, doi: 10.3390/su12177219.

[15] P. Awal, Y. Sudiyani, H. Abimanyu, Y. Sudiyani, and dan Haznan Abimanyu, “"Optimasi Proses Optimasi Proses Perlakuan Awal NaOH Tandan Kosong Kelapa Sawit untuk menjadi Bioetanol Optimization of NaOH Alkali Pretreatment of Oil Palm Empty Fruit Bunch for Bioethanol,” Terap.Indones, vol. 18, no. 1, pp. 27–35, 2016, [Online]. Available: http://kimia.lipi.go.id/inajac/index.php

[16] N. Souza et al., “Progress in Organosolv and Steam Explosion Pretreatments of Oil Palm Fibers for Biomacromolecules Extraction,” Journal of Natural Fibers, vol. 19, pp. 1–15, Nov. 2021, doi: 10.1080/15440478.2021.2002763.

[17] L. J. Xian, B. J. Geng, W. N. A. W. Nadhari, and L. C. Peng, “Optimal Hypochlorite Bleaching Duration for Sesbania grandiflora Pulp,” in IOP Conference Series: Earth and Environmental Science, IOP Publishing Ltd, Dec. 2020. doi: 10.1088/1755-1315/596/1/012011.

Downloads

Published

23/12/2024

How to Cite

[1]
“Efektivitas Delignifikasi Limbah Mesokarp Kelapa Sawit untuk Meningkatkan Potensi Selulosa”, jse, vol. 10, no. 1, Dec. 2024, Accessed: Jan. 09, 2025. [Online]. Available: https://jse.serambimekkah.id/index.php/jse/article/view/606

Similar Articles

11-20 of 121

You may also start an advanced similarity search for this article.