Modification of CaO Catalyst From Chicken Eggshell With Wet Impregnation Method for Two-Stage Process of Biodiesel from Tamanu Oil

Authors

  • Kanesya Najah Abidin Universitas Pembangunan Nasional “Veteran” Jawa Timur Author
  • Reza Gymnastiar Universitas Pembangunan Nasional “Veteran” Jawa Timur Author

Keywords:

biodiesel, FFA content, Impregnation , Tamanu, transesterification, Chicken eggshell

Abstract

Egg production from laying hens in Indonesia is so high that if the egg shells produced are not used properly, they will produce waste. Chicken eggshell waste has a high mineral content, one of which is calcium. Calcium can be utilized as a heterogeneous catalyst which can be used in making renewable energy such as biodiesel. Biodiesel is an alternative energy that is being widely developed because it can be an environmentally friendly alternative to diesel engine fuel. This research aims to determine biodiesel obtained from tamanu oil (Calophyllum inophyllum) by etherification and transesterification processes using a catalyst modified from egg shells using a wet impregnation method using alkaline potassium hydroxide. The catalyst used is the catalyst with the highest alkalinity for making biodiesel. The biodiesel produced had the highest yield of 76.9040% with a density value of 0.94981 gr/ml and a viscosity of 4.11412 cSt.

References

[1] Andya Fanny, W., & Prakoso, T. (2012). pengembangan katalis kalsium oksida untuk sintesis biodiesel. In Jurnal Teknik Kimia Indonesia (Vol. 11, Issue 2).

[2] Aziz, I., Nurbayti, S., & Ulum, B. (2011). Pembuatan produk biodiesel dari Minyak Goreng Bekas dengan Cara Esterifikasi dan Transesterifikasi (Vol. 2, Issue 3).

[3] Bilton, M., Brown, A. P., & Milne, S. J. (2012). Investigating the optimum conditions for the formation of calcium oxide, used for CO2 sequestration, by thermal decomposition of calcium acetate. Journal of Physics: Conference Series, 371. https://doi.org/10.1088/1742-6596/371/1/012075

[4] BSN. (2017). Standar Nasional Indonesia Nyamplung sebagai bahan baku biodisel. www.bsn.go.id

[5] Chua, S. Y., Goh, C. M. H., Tan, Y. H., Mubarak, N. M., Kansedo, J., Khalid, M., ... & Abdullah, E. C. (2020). Biodiesel synthesis using natural solid catalyst derived from biomass waste—A review. Journal of Industrial and Engineering Chemistry, 81, 41-60.

[6] Dweck, A. C., & Meadowsy, T. (2002). Tamanu (Calophyllum inophyllum)-the African, Asian, Polynesian and Pacific Panacea. International Journal of Cosmetic Science, 24, 341–348.

[7] Enggawati, E. R., & Ediati, R. (2013). Pemanfaatan Kulit Telur Ayam dan Abu Layang Batubara sebagai Katalis Heterogen untuk Reaksi Transesterifikasi Minyak Nyamplung (Calophyllum Inophyllum Linn). SAINS DAN SENI POMITS, 2(1), 1–6.

[8] Fanny, W. A., Subagjo, S., & Prakoso, T. (2018). Pengembangan katalis Kalsium Oksida untuk sintesis biodiesel. Jurnal Teknik Kimia Indonesia, 11(2), 66. https://doi.org/10.5614/jtki.2012.11.2.1

[9] Hadi, W. A. (2009). Pemanfaatan Minyak Biji Nyamplung (Calophyllum Inophyllum L) Sebagai Bahan Bakar Minyak Pengganti Solar. Jurnal Riset Daerah, VIII(2), 1044–1052.

[10] Kesić, Ž., Lukić, I., Zdujić, M., Mojović, L., & Skala, D. (2016). Katalizatori na bazi oksida kalcijuma u procesima sinteze biodizela: Presek stanja. In Chemical Industry and Chemical Engineering Quarterly (Vol. 22, Issue 4, pp. 391–408). CI and CEQ. https://doi.org/10.2298/CICEQ160203010K

[11] Krishnan, S. G., Pua, F. ling, & Zhang, F. (2021). A review of magnetic solid catalyst development for sustainable biodiesel production. In Biomass and Bioenergy (Vol. 149). Elsevier Ltd. https://doi.org/10.1016/j.biombioe.2021.106099

[12] Mathew, G. M., Raina, D., Narisetty, V., Kumar, V., Saran, S., Pugazhendi, A., Sindhu, R., Pandey, A., & Binod, P. (2021). Recent advances in biodiesel production: Challenges and solutions. In Science of the Total Environment (Vol. 794). Elsevier B.V. https://doi.org/10.1016/j.scitotenv.2021.148751

[13] Mittlebach, M., & Remschmidt, C. (2004). Biodiesel :The Comprehensive handbook.

[14] Otera, J., & Nishikido, J. (2009). Modern heterogeneous oxidation catalysis : design, reactions and characterization (Vol. 2). Wiley-VCH.

[15] Urasaki, K., Takagi, S., Mukoyama, T., Christopher, J., Urasaki, K., Kato, S., Yamasaki, A., Kojima, T., & Satokawa, S. (2012). Effect of the kinds of alcohols on the structure and stability of calcium oxide catalyst in triolein transesterification reaction. Applied Catalysis A: General, 411–412, 44–50. https://doi.org/10.1016/j.apcata.2011.10.019

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Published

11/07/2025

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How to Cite

[1]
“Modification of CaO Catalyst From Chicken Eggshell With Wet Impregnation Method for Two-Stage Process of Biodiesel from Tamanu Oil”, jse, vol. 10, no. 3, Jul. 2025, Accessed: Oct. 31, 2025. [Online]. Available: https://jse.serambimekkah.id/index.php/jse/article/view/1069

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