Optimalisasi Proses Degumming Minyak Biji Ketapang Menggunakan Asam Fosfat dan NaOH sebagai Bahan Baku Biodiesel

Authors

  • Maliya Syabriyana Universitas Serambi Mekkah Author
  • Zeni Ulma Politeknik Negeri Jember Author
  • Ais Shenly Eka Putri Vinzani Politeknik Negeri Jember Author

Keywords:

Ketapang seed oil , degumming, biodiesel, FFA content, density

Abstract

Ketapang seeds (Terminalia catappa) are a potential source of vegetable oil as a feedstock for biodiesel production. However, the use of ketapang seed oil remains very limited. Degumming is a crucial step in biodiesel production as it determines the quality of the raw material preparation. Various methods can be used to remove gum, including heating and the addition of acids (H3PO4, H2SO4 and HCl) or bases (NaOH). The aim of this study is to maximise the quality of biodiesel feedstock by improving the degumming efficiency using different concentrations of phosphoric acid (H3PO4) and NaOH. The phosphoric acid concentrations used were 0.5%, 1% and 1.5% v/v and the NaOH concentrations were 0.5%, 1% and 1.5% w/w. The degumming process was carried out at 80 °C with stirring for 30 min at each stage. After degumming, ketapang oil has excellent clarity compared to before treatment. Based on the research conducted, the optimum degumming conditions were found at a phosphoric acid concentration of 0.5% v/v and a NaOH mass of 1% w/w, resulting in an FFA content of 0.4% and a density of 902.5 kg/m³.

References

[1] Y. Pasae, L. Bulo, N. Lola, T. T. Seno, and K. Tikupadang, “Produksi Biodiesel Dari Minyak Jelantah Menggunakan Proses Reactive Separation,” in Seminar Nasional Hasil Penelitian & Pengabdian Kepada Masyarakat (SNP2M), 2019, pp. 50–53.

[2] A. P. Mayalibit, Z. L. Sarungallo, and S. N. Paiki, “Pengaruh proses degumming menggunakan asam sitrat terhadap kualitas minyak buah merah (Pandanus conoideus Lamk),” Agritechnology, vol. 2, no. 1, pp. 23–31, 2020.

[3] R. A. Putri, A. Muhammad, and I. Ishak, “Optimasi proses pembuatan biodiesel biji jarak pagar (Jatropha Curcas L.) melalui proses ekstraksi reaktif,” J. Teknol. Kim. Unimal, vol. 6, no. 2, pp. 16–30, 2018.

[4] V. Purnomo, A. S. Hidayatullah, A. Inam, O. P. Prastuti, E. L. Septiani, and R. P. Herwoto, “Biodiesel dari minyak jarak pagar dengan transesterifikasi metanol subkritis,” J. Tek. Kim., vol. 14, no. 2, pp. 73–79, 2020.

[5] D. Ariyani, E. Megawati, P. Ira, A. Sadesi, and M. A. Sugiarto, “Pembuatan Biodiesesl Dan Pengaruh Jenis Pelarut Dan Massa Biji Terhadap% Yield Ekstrak Minyak Biji Ketapang (Terminalia catappa Linn),” PETROGAS J. Energy Technol., vol. 2, no. 1, pp. 51–56, 2020.

[6] N. P. Putri, M. A. Muslim, J. G. Sitorus, D. L. Putra, and M. Marjenah, “Extraction Of Ketapang Seeds (Terminalia Catappa Linn) As Raw Material Of Biodiesel,” Konversi, vol. 7, no. 1, pp. 10–14, 2019.

[7] F. M. A. Chusna, S. Cahaya, and S. Aprianita, “Optimasi Pembuatan Bioetanol dari Limbah Bonggol Jagung Berdasarkan Beda Waktu Fermentasi dan Berat Ragi,” J. Serambi Eng., vol. 9, no. 1, pp. 8140–8145, 2024.

[8] F. Febriyanti, I. Sofianty, A. G. P. Sari, R. F. Madani, M. R. Bilad, and A. B. D. Nandiyanto, “Fluidized Bed Reactor Type: Reactor Design for Biodiesel Production from Soybean Oil Using MgO Catalyst,” J. Earth Energy Sci. Eng. Technol., vol. 5, no. 2, 2022.

[9] S. Oko, M. Mustafa, A. Kurniawan, and D. Willain, “Sintesis Biodiesel Dari Minyak Kedelai Melalui Reaksi Transesterifikasi Dengan Katalis CaO/NaOH,” J. Teknol., vol. 13, no. 1, pp. 1–6, 2021.

[10] J. P. Susanto, A. D. Santoso, and N. Suwedi, “Perhitungan potensi limbah padat kelapa sawit untuk sumber energi terbaharukan dengan metode LCA,” J. Teknol. Lingkung., vol. 18, no. 2, pp. 165–172, 2017.

[11] N. Abdurrojaq et al., “Perbandingan Uji Densitas Menggunakan Metode ASTM D1298 dengan ASTM D4052 pada Biodiesel Berbasis Kelapa Sawit,” Lembaran Publ. Miny. dan gas bumi, vol. 55, no. 1, pp. 49–57, 2021.

[12] D. A. Prasetyo, M. R. A. Saputro, and Z. Ulma, “Arang Kulit Biji Kakao (Theobroma cacao L) sebagai Adsorben untuk Menurunkan Kadar Asam Lemak Bebas pada Pembuatan Biodiesel dari Minyak Jelantah,” J. Tek. Terap., vol. 2, no. 1, pp. 25–35, 2023.

[13] I. Rizal, “Sintesis Coco-Biodiesel Dari Minyak Kelapa Mentah (Crude Coconut Oil) Menggunakan Static Mixer,” Indones. J. Ind. Res., vol. 36, no. 2, pp. 73–82, 2019.

[14] N. K. Erliyanti, A. K. Sari, A. Chumaidi, R. R. Yogaswara, and E. A. Saputro, “Transesterification Of Biodiesel From Kapok Seed Oil (Ceiba pentandra),” Konversi, vol. 10, no. 2, 2021.

[15] R. Rahmaniar, “Minyak Biji Ketapang (Terminalia Catappa L) sebagai Bahan Pelunak dalam Pembuatan Kompon Karet,” J. Din. Penelit. Ind., vol. 24, no. 1, pp. 49–56, 2013.

[16] N. Hidayat, “Pengaruh Lama Waktu Pengadukan dan Konsentrasi NaOH pada Proses Pemurnian Minyak Goreng Superworm (Zophobas morio),” 2018.

[17] D. Hasahatan, J. Sunaryo, and L. N. Komariah, “Pengaruh ratio H2SO4 dan waktu reaksi terhadap kuantitas dan kualitas biodiesel dari minyak jarak pagar,” J. Tek. Kim., vol. 18, no. 2, pp. 26–36, 2012.

[18] M. Alamsyah and R. Kalla, “Pemurnian minyak jelantah dengan proses adsorbsi,” J. Chem. Process Eng., vol. 2, no. 2, pp. 22–26, 2017.

[19] S. D. Purwaningrum and S. Sukaryo, “Uji Karakteristik Biodiesel Berbahan Dasar Limbah Jeroan Ikan Diproses Menggunakan Mikrogelombang,” METANA, vol. 14, no. 2, pp. 37–42, 2018.

Downloads

Published

23/10/2024

How to Cite

[1]
“Optimalisasi Proses Degumming Minyak Biji Ketapang Menggunakan Asam Fosfat dan NaOH sebagai Bahan Baku Biodiesel”, jse, vol. 9, no. 4, Oct. 2024, Accessed: Nov. 14, 2024. [Online]. Available: https://jse.serambimekkah.id/index.php/jse/article/view/595

Similar Articles

11-20 of 88

You may also start an advanced similarity search for this article.