Initial Treatment For Lithium And Boron Extraction From PT Pertamina Geothermal Energy Tbk Brine Via Chemical Precipitation For Sustainable Energy Transition

Authors

  • Bogie Lesmana Politeknik Negeri Sriwijaya Author
  • Bima Bharata Shena Politeknik Negeri Sriwijaya Author
  • Martha Aznury Politeknik Negeri Sriwijaya Author
  • Dilia Puspa Politeknik Negeri Sriwijaya Author
  • Anerasari Meidinariasty Politeknik Negeri Sriwijaya Author

Keywords:

Lithium extraction, Boron recovery, Geothermal brine, Chemical precipitation, Sustainable energy transition

Abstract

The increasing demand for critical minerals such as lithium and boron is driven by the rapid growth of electric vehicles, clean energy transition, and sustainable material applications. Geothermal brine, a by-product of geothermal power generation, offers significant potential as an alternative source of these elements. This study investigated the extraction of lithium and boron from geothermal brine sourced from PT Pertamina Geothermal Energy Tbk, Lumut Balai Area. Lithium was recovered using a chemical precipitation method with sodium carbonate (Na₂CO₃) at 80°C and pH 11, while boron was extracted via liquid–liquid extraction using 2-ethyl-1-hexanol in kerosene. For lithium, various reagent-to-brine ratios (1:5, 1:10, 1:15) and precipitation times (15–75 minutes) were tested, with optimal conditions at a 1:15 ratio and 60 minutes, yielding 28.9 ppm lithium and a 129.08% yield. For boron, the highest concentration of 43.6 ppm was obtained at a 1.5:1 phase ratio and 75 minutes, with subsequent purification returning boron to the aqueous phase. Application testing showed that the boron–borax mixture provided higher wood preservation performance (1.332 kg/m³) compared to pure borax (1.13 kg/m³), meeting SNI 03-5003.1-1999 standards. These findings demonstrate that geothermal brine can serve as a dual source of lithium and boron, supporting sustainable energy transition and eco-friendly material development in Indonesia.

Author Biographies

  • Bogie Lesmana, Politeknik Negeri Sriwijaya

    D4 TEKNOLOGI KIMIA INDUSTRI
    JURUSAN TEKNIK KIMIA
    POLITEKNIK NEGERI SRIWIJAYA

  • Bima Bharata Shena, Politeknik Negeri Sriwijaya

    D4 TEKNOLOGI KIMIA INDUSTRI
    JURUSAN TEKNIK KIMIA
    POLITEKNIK NEGERI SRIWIJAYA

  • Martha Aznury, Politeknik Negeri Sriwijaya

    Dosen Jurusan Teknik Kimia
    Politeknik Negeri Sriwijaya

  • Dilia Puspa, Politeknik Negeri Sriwijaya

    Dosen Jurusan Teknik Kimia
    Politeknik Negeri Sriwijaya

  • Anerasari Meidinariasty, Politeknik Negeri Sriwijaya

    Dosen jurusan Teknik Kimia

    Politeknik Negeri Sriwijaya

References

[1] A. F. Hakim et al., “Indonesian Journal of Conservation,” Indonesian Journal of Conservation, vol. 11, no. 2, pp. 71–77, 2022, doi: 10.15294/ijc.v11i2.40599.

[2] U. S. G. Survey, “Mineral Commodity Summaries 2023,” Mineral Commodity Summaries, 2023, doi: 10.3133/MCS2023.

[3] M. F. Khasmadin and U. Harmoko, “Kajian Potensi dan Pemanfaatan Energi Panas Bumi di Wilayah Kerja Panas Bumi Patuha Ciwidey,” Jurnal Energi Baru dan Terbarukan, vol. 2, no. 2, pp. 101–113, Jul. 2021, doi: 10.14710/jebt.2021.11187.

[4] A. Cerda, M. Jara, O. Yañez, Y. Barrueto, and Y. P. Jimenez, “Boron Recovery from Organic Solutions Used in Brine Treatment through a Water Stream,” Minerals, vol. 14, no. 3, Mar. 2024, doi: 10.3390/min14030265.

[5] X. Peng, D. Shi, Y. Zhang, L. Zhang, L. Ji, and L. Li, “Recovery of boron from unacidified salt lake brine by solvent extraction with 2,2,4-trimethyl-1,3-pentanediol,” Sep. 10, 2020. doi: 10.22541/au.159969857.76153352.

[6] W. Cheng, Z. Li, and F. Cheng, “Solubility of Li2CO3 in Na-K-Li-Cl brines from 20 to 90 °c,” Journal of Chemical Thermodynamics, vol. 67, pp. 74–82, 2013, doi: 10.1016/j.jct.2013.07.024.

[7] A. F. Kiemde, J. Marin, V. Flexer, and A. Chagnes, “Liquid-liquid extraction of boron from continental brines by 2-butyl-1-octanol diluted in kerosene,” RSC Adv, vol. 14, no. 4, pp. 2170–2181, Jan. 2024, doi: 10.1039/d3ra08045e.

[8] N. Linneen, R. Bhave, and D. Woerner, “Purification of industrial grade lithium chloride for the recovery of high purity battery grade lithium carbonate,” Sep Purif Technol, pp. 168–173, May 2019, doi: 10.1016/j.seppur.2018.05.020.

[9] Y. Zhang, Y. Hu, L. Wang, and W. Sun, “Systematic review of lithium extraction from salt-lake brines via precipitation approaches,” Aug. 01, 2019, Elsevier Ltd. doi: 10.1016/j.mineng.2019.105868.

[10] V. Flexer, C. F. Baspineiro, and C. I. Galli, “Lithium recovery from brines: A vital raw material for green energies with a potential environmental impact in its mining and processing,” Oct. 15, 2018, Elsevier B.V. doi: 10.1016/j.scitotenv.2018.05.223.

[11] IEA, “Critical Minerals Data Explorer – Data Tools - IEA.” Accessed: Aug. 06, 2025. [Online]. Available: https://www.iea.org/data-and-statistics/data-tools/critical-minerals-data-explorer

[12] H. Nikkhah, A. Di Maria, G. Granata, and B. Beykal, “Sustainable process design for lithium recovery from geothermal brines using chemical precipitation,” Resour Conserv Recycl, vol. 212, Jan. 2025, doi: 10.1016/j.resconrec.2024.107980.

[13] S. Toprak, Ç. Öncel, S. Yılmaz, A. Baba, G. A. Koç, and M. M. Demir, “Lithium extraction from geothermal brine using γ-MnO2: A case study for Tuzla geothermal power plant,” Heliyon, vol. 10, no. 21, Nov. 2024, doi: 10.1016/j.heliyon.2024.e39656.

[14] A. F. Kiemde, J. Marin, V. Flexer, and A. Chagnes, “Boron extraction by aliphatic mono- and di-hydroxy alcohols from a representative continental brine,” Hydrometallurgy, vol. 225, Apr. 2024, doi: 10.1016/j.hydromet.2024.106280.

[15] F. Deniz and C. Akarsu, “Operating Cost and Treatment of Boron from Aqueous Solutions by Electrocoagulation in Low Concentration,” Global Challenges, vol. 2, no. 5–6, Jun. 2018, doi: 10.1002/gch2.201800011.

[16] H. Nikkhah et al., “Challenges and opportunities of recovering lithium from seawater, produced water, geothermal brines, and salt lakes using conventional and emerging technologies,” Oct. 15, 2024, Elsevier B.V. doi: 10.1016/j.cej.2024.155349.

[17] S. Kim, H. Joo, T. Moon, S.-H. Kim, and J. Yoon, “Supplementary Information Rapid and selective lithium recovery from desalination brine using an electrochemical system,” 2019.

[18] A. Cipollina et al., “Recovery of Lithium Carbonate from Dilute Li-Rich Brine via Homogenous and Heterogeneous Precipitation,” Ind Eng Chem Res, vol. 61, no. 36, pp. 13589–13602, Sep. 2022, doi: 10.1021/acs.iecr.2c01397.

[19] Z. Xu et al., “Recovery of boron from brines with high magnesium content by solvent extraction using aliphatic alcohol,” RSC Adv, vol. 11, no. 26, pp. 16096–16105, Apr. 2021, doi: 10.1039/d1ra01906f.

[20] W. L. A. Brooks, C. C. Deng, and B. S. Sumerlin, “Structure-Reactivity Relationships in Boronic Acid-Diol Complexation,” ACS Omega, vol. 3, no. 12, pp. 17863–17870, Dec. 2018, doi: 10.1021/acsomega.8b02999.

[21] Dwynda, Indra, and Rahadian Zainul. "Boric Acid (H3 (BO3): Recognize The Molecular Interactions in Solutions." INA-Rxiv: Bandung, Indonesia (2018).

[22] N. Jakubowski and N. J. S. Becker, “Inorganic mass spectrometry. Principles and applications,” https://doi.org/10.1007/s00216-008-2374-4, vol. 392, pp. 775–776, 2008.

[23] A. C. Alera, J. P. Benitez, R. J. Fernandez, C. K. Pascual, F. Policarpio, and E. C. R. Lopez, “Recent Advances in Lithium Extraction,” in The 3rd International Electronic Conference on Processes, Basel Switzerland: MDPI, Sep. 2024, p. 52. doi: 10.3390/engproc2024067052.

Downloads

Published

04/10/2025

How to Cite

[1]
“Initial Treatment For Lithium And Boron Extraction From PT Pertamina Geothermal Energy Tbk Brine Via Chemical Precipitation For Sustainable Energy Transition”, jse, vol. 10, no. 4, Oct. 2025, Accessed: May 23, 2026. [Online]. Available: https://jse.serambimekkah.id/index.php/jse/article/view/1230

Most read articles by the same author(s)

Similar Articles

31-40 of 361

You may also start an advanced similarity search for this article.