Perbandingan Adsorpsi dan Injeksi Hidrogen Peroksida Setelah Proses Sequencing Batch Reactor untuk Pengolahan Bahan Organik Limbah Cair Kecap

Mochammad Rifki Fiakhsani Taqwim; Novirina Hendrasarie

Authors

Mochammad Rifki Fiakhsani Taqwim Universitas Pembangunan Nasional “Veteran” Jawa Timur Author
Novirina Hendrasarie Universitas Pembangunan Nasional “Veteran” Jawa Timur Author

Keywords:

Wastewater Treatment, Biological Treatment, Adsorption, Adsorbent, Hydrogen Peroxide

Abstract

The characteristics of soy sauce industry wastewater, which contains high levels of organic matter from the production process, can pollute the environment physically, chemically, and biologically. This study aims to analyze the effectiveness of treatment on the parameters of Chemical Oxygen Demand (COD), Total Suspended Solids (TSS), Total Dissolved Solids (TDS), and Total Nitrogen (TN). Post-treatment was conducted after a Sequencing Batch Reactor (SBR) using an adsorption process with variations of commercial adsorbents and crab shell-based adsorbents. It was then compared with the injection of Hydrogen Peroxide (H₂O₂) at varying doses of 0.25, 0.5, and 1 mL/L. The results of the initial test analysis of soy sauce liquid waste were found to exceed the soy sauce wastewater quality standards. The optimal SBR condition was achieved at a Hydraulic Retention Time (HRT) of 48 hours. The best post-treatment results were obtained using natural crab shell adsorbents, with removal efficiencies of COD 87.3%, TSS 96.4%, TDS 85.6%, and TN 90%. For H₂O₂ dosing, the 1 mL/L variation showed the highest removal: COD 70.3%, TSS 82.1%, TDS 50%, and TN 70%. These results indicate that the advanced treatment effectively reduced pollutants to meet regulatory standards.

References

[1] Z. Oktaviani and N. Hendrasarie, “Efektivitas Konsorsium Mikroalga Chlorella sp . dan Mikroba Indigenous Dalam Menurunkan BOD , COD , dan TN Air Limbah Industri Kecap Menggunakan MBBR,” vol. IX, no. 4, pp. 10724–10730, 2024.

[2] Y. F. Ardiansyah and M. Mirwan, “Eco Enzim sebagai Larutan Pendukung untuk Menurunkan TSS dan COD Pada Air Limbah Tahu dengan Proses Anaerob,” vol. IX, no. 2, pp. 9023–9029, 2024.

[3] A. D. Yospy Guntur, A. N. Wibowo Jati, and L. Indah Murwani Yulianti, “Perbaikan Kualitas Limbah Cair Industri Kecap Dan Saos Pt. Lombok Gandaria Dengan Variasi Bakteri Indigenus Quality Improvement of Ketchup and soy Sauce’s Industrial Liquid Waste in PT. Lombok Gandaria with Indigenous Bacteria Variance,” 2017.

[4] I. I. Yadaturrahmah, “Pengaruh Penambahan Impeller Pada Fase Aerobik Terhadap Efisiensi Kinerja Sequencing Batch Reactor Pada Limbah Cair Industri Tahu,” Univ. Pembang. Nas. “Veteran” Jawa Timur, 2020.

[5] H. Mulyani, G. P. I. Budianto, M. Margono, and M. Kaavessina, “Study of COD Removal Rate on a Sequencing Batch Reactor (SBR) Treating Tapioca Wastewater,” agriTECH, vol. 38, no. 3, p. 243, 2019, doi: 10.22146/agritech.29271.

[6] N. Hendrasarie and F. Febriana, “Efektivitas Penambahan Serabut Kelapa Dan Kulit Buah Siwalan Sebagai Adsorben Dan Media Lekat Biofilm Pada Pengolahan Limbah Domestik Menggunakan Sequencing Batch Reactor,” J. Envirotek, vol. 14, no. 1, pp. 98–105, 2022, doi: 10.33005/envirotek.v14i1.182.

[7] E. Adriansyah, M. Marhadi, P. Herawati, H. Viareco, R. Sufra, and T. Emilia Agustina, “Advanced Treatment of Tofu Wastewater using Multilevel Filtration and TiO2 Photocatalysis as Promising Approach for Effective Wastewater Remediation,” J. Presipitasi Media Komun. dan Pengemb. Tek. Lingkung., vol. 20, no. 3, pp. 560–571, 2023, doi: 10.14710/presipitasi.v20i3.560-571.

[8] A. H. Ahmad, T., Belhaj, H., Al-Muhtaseb, “Adsorption of emerging organic contaminants by activated carbon from wastewater: A review,” Environ. Technol. Innov., 2020.

[9] D. R. Rais and O. Setiawan, “Pengolahan limbah cair industri sarung dengan metode fenton Treatment of sarong industrial liquid waste by fenton method,” J. Integr. Proses dan Lingkung., vol. 1, no. 2, pp. 55–61, 2024, [Online]. Available: http://ejournal.ft.umg.ac.id/index.php/jtk.

[10] P. W. N. Wang, T. Zheng, G. Zhang, “A review on Fenton-like processes for organic wastewater treatment,” J. Environ. Chem. Eng., vol. 4(1), pp. 762–787, 2016.

[11] S. Riztu et al., “Penurunan Kadar COD Air Limbah Domestik Menggunakan Fly Ash d engan Metode Adsorpsi,” vol. 24, no. 3, pp. 2570–2574, 2024, doi: 10.33087/jiubj.v24i3.5677.

[12] H. Ababneh and B. H. Hameed, “Chitosan-derived hydrothermally carbonized materials and its applications: A review of recent literature,” Int. J. Biol. Macromol., vol. 186, pp. 314–327, 2021, [Online]. Available: https://www.sciencedirect.com/science/article/pii/S0141813021013908.

[13] H. Novirina and F. I. Zarfandi, “Integrated Anoxic-Oxic Sequencing Batch Reactor Combined with Coconut Fiber Waste as Biofilm and Adsorbent Media,” J. Ecol. Eng., vol. 24, no. 11, pp. 176–189, 2023, doi: 10.12911/22998993/170994.

[14] D. Soroosh, H., Otterpohl, R., & Hanelt, “Influence of hydraulic retention time on municipal wastewater treatment using microalgae‑bacteria flocs in sequencing batch reactors.,” Bioresour. Technol. Reports, 2022, [Online]. Available: https://doi.org/10.1016/j.biteb.2021.100884.

[15] N. Hendrasarie, A. N. Ramadhani, F. Rosariawari, and A. Amalia, “Hybrid Biofilter-Adsorption Performance to Removal Organic Matter and Color on Black Soybean Sauce Wastewater,” IOP Conf. Ser. Earth Environ. Sci., vol. 1454, no. 1, 2025, doi: 10.1088/1755-1315/1454/1/012030.

[16] J. Wu, S. X., & Maskaly, “Study on the effect of total dissolved solids (TDS) on the performance of an SBR for COD and nutrients removal.,” J. Ilmu Lingkung. Kesehat. Zat Berbahaya Toksin Lingkung., 2018, [Online]. Available: https://pubmed.ncbi.nlm.nih.gov/29111848/.

[17] J. Ding, Y., Zhao, J., Wang, “Enhanced nitrogen removal by alternating aerobic/anoxic phases in a sequencing batch reactor: Performance and microbial characteristics,” Bioresour. Technol. Reports, vol. 351, 2022, [Online]. Available: https://doi.org/10.1016/j.biortech.2022.127039.

[18] Azalia Amelinda Thomasina & Novirina Hendrasarie, “Wastewater Treatment of Npk Fertilizer Industry Using Sequencing Batch Reactor and Granular Activated Carbon,” J. Enviromental Eng. Sustain. Technol., vol. 9, no. 2, pp. 83–90, 2022, doi: 10.21776/ub.jeest.2022.009.02.6.

[19] A. A. Babaei and F. Ghanbari, “COD removal from petrochemical wastewater by UV/hydrogen peroxide, UV/persulfate and UV/percarbonate: Biodegradability improvement and cost evaluation,” J. Water Reuse Desalin., vol. 6, no. 4, pp. 484–494, 2016, doi: 10.2166/wrd.2016.188.

[20] R. Ursada, Z. J. Alfani, and A. Y. Bagastyo, “Treatment of leachate from Bantargebang Landfill using oxidation process with H 2 O 2,” vol. 7, no. 2, 2023.

[21] M. E. M. Mahmoud, T. A. M. Abd El-Razek, H. S. Abd El- Rahman, and M. A. Saad, “Enhancing Effluent Quality of Wastewater Treatment Plants Using Advanced Oxidation Process,” J. Environ. Sci., vol. 50, no. 10, pp. 543–578, 2021, doi: 10.21608/jes.2021.206547.

[22] K. U. Henggu et al., “Modifikasi Kitosan Dari Limbah Cangkang Kepiting Sebagai Sediaan Material Membran Filtrasi Air,” Jambura Fish Process. J., vol. 4, no. 2, pp. 72–82, 2022, doi: 10.37905/jfpj.v4i2.13807.

[23] E. Siswoyo, R. N. Zahra, N. H. A. Mai, A. Nurmiyanto, K. Umemura, and T. Boving, “Chitosan of blood cockle shell (Anadara granosa) as a natural coagulant for removal of total suspended solids (TSS) and turbidity of well-water,” Egypt. J. Aquat. Res., vol. 49, no. 3, pp. 283–289, 2023, doi: 10.1016/j.ejar.2023.04.004.

[24] C. Y. Chuppa Tostain G, Tan M, Adelard L, ShumCheong-Sing A, François JM and P. T, “Evaluation of filamentous fungi and yeasts for the biodegradation of sugarcane distillery wastewater,” Microorganisms, vol. 8(10), pp. 1–16, 2020.

[25] N. . Vida, F. & Hendrasarie, “Spent Bleaching Earth sebagai Adsorben untuk Menyisihkan Krom dan Warna pada Limbah Cair Batik,” J. Serambi Eng., vol. 9, no. 1, pp. 7642–7653, 2023, doi: 10.32672/jse.v9i1.722.

[26] J.-Y. Y.-S. X. a. M.-X. L. R. J. L.-S. Z. B.-H. F. Tang, “Hyperbranched polyethyleneimine-functionalised chitosan aerogel for highly efficient removal of melanoidins from wastewater,” J. Hazard. Mater., vol. 447, 2023, [Online]. Available: https://www.sciencedirect.com/science/article/abs/pii/S0304389423000134?via%3Dihub.

[27] T. I. Liakos and N. K. Lazaridis, “Melanoidin removal from molasses effluents by adsorption,” J. Water Process Eng., vol. 10, pp. 156–164, 2016.